{"id":16,"date":"2012-09-30T18:22:20","date_gmt":"2012-09-30T18:22:20","guid":{"rendered":"http:\/\/www.ipalchemist.com\/blog\/?page_id=16"},"modified":"2012-10-05T10:33:26","modified_gmt":"2012-10-05T10:33:26","slug":"chemistry","status":"publish","type":"page","link":"https:\/\/www.ipalchemist.com\/blog\/chemistry\/","title":{"rendered":"Chemistry"},"content":{"rendered":"<p>I studied chemistry at Oxford University, where I was at New College.\u00a0 (Before you ask, I didn\u2019t sing in New College choir, as I was not of that standard.\u00a0 I moonlighted at Oriel, and occasionally at Queen\u2019s and Balliol.\u00a0 But that belongs on the Music page.)<\/p>\n<p>My Part II (4th year undergraduate research) project was supervised by Dr Gordon Whitham, a wonderful chemist of the old school.\u00a0 It was about free-radical-mediated rearrangements of allylic sulphones, sulphoxides, and thioethers.\u00a0 But where sulphoxides got involved, sigmatropic rearrangements took over.<\/p>\n<p>For my DPhil (that is Oxford-speak for PhD) I worked in the laboratories of Dr (now Professor) Stephen Davies.\u00a0 I concentrated on synthetic organic chemistry, in\u00a0particular finding synthetic applications of a\u00a0route to enantiomerically pure beta-amino esters that had been developed in the group a little earlier.\u00a0 Unimaginatively, my thesis was called \u201cAsymmetric synthesis via beta-amino esters\u201d.\u00a0 In my favourite part, I combined the existing methodology with a Meisenheimer rearrangement to make 1,5-dihydroxy compounds; and with a Cope elimination to make asymmetric Baylis-Hillman adducts.\u00a0 I also made daunosamine and an epimer of it, but that was not as elegant as I had hoped.\u00a0 But it was my first exposure to sugar chemistry, which remains an interest.\u00a0 My internal examiner was Dr George Fleet, a leading carbohydrate chemist.<\/p>\n<p>I did a two-year post-doc in Japan at the Tokyo Institute of Technology, in the laboratory of Professor Koichi Mikami.\u00a0 I am very grateful for his kindness \u2013 I was the first post-doc in his laboratory (and indeed in his department), and he made me very welcome.\u00a0 I was working with oxonium-ene reactions, in particular intramolecular variants.\u00a0 I had a very enthusiastic student, now Dr Hirofumi Ohmura, who is now a researcher at Astellas.\u00a0 I was funded at that time by a fellowship from the Royal Society and the Japan Society for the Promotion of Science.<\/p>\n<p>I now practise primarily in the field of chemical patents, but in a very wide range of chemistry.<\/p>\n<p>I am a member of:<\/p>\n<p>The Royal Society of Chemistry (<a title=\"Royal Society of Chemistry\" href=\"http:\/\/www.rsc.org\/\" target=\"_blank\">RSC<\/a>)<\/p>\n<p>The Society of Chemical Industry (<a title=\"The Society of Chemical Industry\" href=\"http:\/\/www.soci.org\/\" target=\"_blank\">SCI<\/a>)<\/p>\n<p>The Society of Dyers and Colourists (<a title=\"Society of Dyers and Colourists\" href=\"http:\/\/www.sdc.org.uk\/\" target=\"_blank\">SDC<\/a>)<\/p>\n<p>On four occasions since 2006 I have been involved in organising and presenting a one day course called \u201cWhat a chemist needs to know about patents\u201d for members of the SCI.\u00a0 We hope to repeat in late 2013 or early\u00a02014.<\/p>\n<p>It distresses me that in normal discourse \u201cchemical\u201d is synonymous with \u201ctoxic\u201d and, conversely, \u201cnatural\u201d is a synonym for \u201chealthy\u201d. \u00a0\u201dNatural\u201d and \u201cchemical\u201d are not usually capable of existing in the same meme. \u00a0A number of chemist bloggers that I follow highlight examples of what has been named \u201cchemophobia\u201d, which crop up in the labelling of everything, from foods and cosmetics, where one might expect it, all the way through to (I am not making it up) chemistry sets for children. \u00a0(Look up the Twitter hashtag.) I find myself wanting to shout rather often \u201cStrychnine is natural! \u00a0Chemicals are everywhere and everything!\u201d. \u00a0 I don\u2019t, of course. \u00a0I just resort to thinking harsh thoughts, occasionally tweeting, and now blogging.<\/p>\n<p>I will post about chemistry and science matters from time to time. \u00a0I hope to highlight example of chemophobia when I find them.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>I studied chemistry at Oxford University, where I was at New College.\u00a0 (Before you ask, I didn\u2019t sing in New &#8230; <br \/><a class=\"more-link\" href=\"https:\/\/www.ipalchemist.com\/blog\/chemistry\/\">keep reading<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-16","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/www.ipalchemist.com\/blog\/wp-json\/wp\/v2\/pages\/16"}],"collection":[{"href":"https:\/\/www.ipalchemist.com\/blog\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.ipalchemist.com\/blog\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.ipalchemist.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.ipalchemist.com\/blog\/wp-json\/wp\/v2\/comments?post=16"}],"version-history":[{"count":2,"href":"https:\/\/www.ipalchemist.com\/blog\/wp-json\/wp\/v2\/pages\/16\/revisions"}],"predecessor-version":[{"id":63,"href":"https:\/\/www.ipalchemist.com\/blog\/wp-json\/wp\/v2\/pages\/16\/revisions\/63"}],"wp:attachment":[{"href":"https:\/\/www.ipalchemist.com\/blog\/wp-json\/wp\/v2\/media?parent=16"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}